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J Korean Soc Environ Eng > Volume 38(8); 2016 > Article
J Korean Soc Environ Eng 2016;38(8): 411-419. doi: https://doi.org/10.4491/KSEE.2016.38.8.411
재순환방식 튜브형 전해모듈시스템을 이용한 안료폐수의 전기화학적 산화
정종식
욱성화학(주) 기술연구소
Electrochemical Oxidation of Pigment Wastewater Using the Tube Type Electrolysis Module System with Recirculation
Jong Sik Jeong
R&D Center of Ukseung Chemical Co., Ltd
Corresponding author  Jong Sik Jeong ,Tel: 051-718-5307, Fax: 051-528-9974, Email: jsiksun@ukseung.co.kr
Received: February 22, 2016;  Revised: June 22, 2016;  Accepted: July 15, 2016.  Published online: August 31, 2016.
ABSTRACT
The objective of this study was to evaluate the application possibility of tube type electrolysis module system using recirculation process through removal organic matters and nitrogen in the pigment wastewater. The tube type electrolysis module consisted of a inner rod anode and an outer tube cathode. Material used for anode was titanium electroplated with RuO2. Stainless steel was used for cathode. It was observed that the pollutant removal efficiency was increased according to the decrease of flowrate and increase of current density. When the retention time in tube type electrolysis module system was 180 min, chlorate concentration was 382.4~519.6 mg/L. The chlorate production was one of the major factors in electrochemical oxidation of tube type electrolysis module system using recirculation process used in this research. The pollutant removal efficiencies from the bench scale tube type electrolysis module system using recirculation operated under the electric charge of 4,500 C/dm2 showed the CODMn 89.6%, CODCr 67.8%, T-N 96.8%, and Color 74.2%, respectively and energy consumption was 5.18 kWh/m3.
Key Words: Tube Type, Electrolysis Module System, Recirculation, Electrochemical Oxidation, Pigment Wastewater
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