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| 세척기반처리에 의한 해양오염퇴적물에 함유된 유기 오염물질 제거 공정 중 중금속 처리 가능성 |
| 심영섭1,2, 김경련1, 김석현1,2 |
1한국해양과학기술원
2과학기술연합대학원대학교 |
| Treatability of Heavy Metals in the Washing Technology of Marine Sediments Contaminated with Organic Matter |
| Young Sub Sim1,2, Kyoung Rean Kim1, Suk Hyun Kim1,2 |
1Korea Institute of Ocean Science and Technology
2University of Science and Technology |
| Corresponding author |
Kyoung Rean Kim ,Tel: 031-400-6185, Fax: 031-408-4493, Email: kyoungrean@kiost.ac
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Received: December 8, 2014; Revised: December 17, 2014; Accepted: December 26, 2014. Published online: December 31, 2014. |
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| ABSTRACT |
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Treatability of heavy metals in marine sediments contaminated with mainly organic matter was investigated on the basis of washing technology using oxidizers and surfactants. Sediment samples were collected at N area which expected for remediation project of contaminated marine sediment. For additives, hydrogen peroxide (H2O2) and Tween-80 were used at oxidizer and non-ionic surfactant, respectively. In experiments, sediments was mixed with sea water at the ratio of 1 : 3 than H2O2 (1 M, 3 M, 4 M, 5 M) and Tween-80 (0.05%) were added. Samples were gathered at following reaction time (10, 20, 30, 40, 50, 60, 70, 80 min and 24 h). Total Organic Carbon (TOC) was 55.2% at the conditions of 5 M H2O2 + 0.05% Tween-80 24 h. Hence total heavy metals were Cu 29.5%, Zn 42.3%, Cd 73.0% and bioavailable heavy metals were Cu 60.0%, Zn 77.7%, Cd 90.2% at the conditions of 5 M H2O2 + 0.05% Tween-80 10 min. The correlations for between bioavailable metals (Cu, Zn, Cd) and TOC were significant (Cu, Zn, Cd; r2 = 0.94, 0.85, 0.69, respectively). |
| Key Words:
Contaminated Marine Sediments, Remediation, Heavy Metals, Additives, Washing Technology |
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